Measurement of LNAPL flow using single-well tracer dilution techniques   总被引：1，自引：0，他引：1  

Sale T  Taylor GR  Iltis G  Lyverse M 《Ground water》2007,45(5):569-578

This paper describes the use of single-well tracer dilution techniques to resolve the rate of light nonaqueous phase liquid (LNAPL) flow through wells and the adjacent geologic formation. Laboratory studies are presented in which a fluorescing tracer is added to LNAPL in wells. An in-well mixer keeps the tracer well mixed in the LNAPL. Tracer concentrations in LNAPL are measured through time using a fiber optic cable and a spectrometer. Results indicate that the rate of tracer depletion is proportional to the rate of LNAPL flow through the well and the adjacent formation. Tracer dilution methods are demonstrated for vertically averaged LNAPL Darcy velocities of 0.00048 to 0.11 m/d and LNAPL thicknesses of 9 to 24 cm. Over the range of conditions studied, results agree closely with steady-state LNAPL flow rates imposed by pumping. A key parameter for estimating LNAPL flow rates in the formation is the flow convergence factor alpha. Measured convergence factors for 0.030-inch wire wrap, 0.030-inch-slotted polyvinyl chloride (PVC), and 0.010-inch-slotted PVC are 1.7, 0.91, and 0.79, respectively. In addition, methods for using tracer dilution data to determine formation transmissivity to LNAPL are presented. Results suggest that single-well tracer dilution techniques are a viable approach for measuring in situ LNAPL flow and formation transmissivity to LNAPL.  相似文献   

Phosphorus and iron cycling in deep saprolite,Luquillo Mountains,Puerto Rico     

Heather L. Buss  Ryan Mathur  Arthur F. White  Susan L. Brantley 《Chemical Geology》2010,269(1-2):52-61

Rapid weathering and erosion rates in mountainous tropical watersheds lead to highly variable soil and saprolite thicknesses which in turn impact nutrient fluxes and biological populations. In the Luquillo Mountains of Puerto Rico, a 5-m thick saprolite contains high microorganism densities at the surface and at depth overlying bedrock. We test the hypotheses that the organisms at depth are limited by the availability of two nutrients, P and Fe. Many tropical soils are P-limited, rather than N-limited, and dissolution of apatite is the dominant source of P. We document patterns of apatite weathering and of bioavailable Fe derived from the weathering of primary minerals hornblende and biotite in cores augered to 7.5 m on a ridgetop as compared to spheroidally weathering bedrock sampled in a nearby roadcut.Iron isotopic compositions of 0.5 N HCl extracts of soil and saprolite range from about δ⁵⁶Fe = 0 to ? 0.1‰ throughout the saprolite except at the surface and at 5 m depth where δ⁵⁶Fe = ? 0.26 to ? 0.64‰. The enrichment of light isotopes in HCl-extractable Fe in the soil and at the saprolite–bedrock interface is consistent with active Fe cycling and consistent with the locations of high cell densities and Fe(II)-oxidizing bacteria, identified previously. To evaluate the potential P-limitation of Fe-cycling bacteria in the profile, solid-state concentrations of P were measured as a function of depth in the soil, saprolite, and weathering bedrock. Weathering apatite crystals were examined in thin sections and an apatite dissolution rate of 6.8 × 10^? 14 mol m^? 2 s^? 1 was calculated. While surface communities depend on recycled nutrients and atmospheric inputs, deep communities survive primarily on nutrients released by the weathering bedrock and thus are tightly coupled to processes related to saprolite formation including mineral weathering. While low available P may limit microbial activity within the middle saprolite, fluxes of P from apatite weathering should be sufficient to support robust growth of microorganisms in the deep saprolite.  相似文献   

The host stars of extrasolar planets have normal lithium abundances     

Sean G. Ryan 《Monthly notices of the Royal Astronomical Society》2000,316(3):L35-L39

The lithium abundances of planet-harbouring stars have been compared with the lithium abundances of open clusters and field stars. Young (chromospherically active) and subgiant stars have been eliminated from the comparison because they are at different stages of evolution and Li processing than the planet-harbouring stars, and hence have systematically higher Li abundances. The analysis showed that the Li abundances of the planet-harbouring stars are indistinguishable from those of non-planet-harbouring stars of the same age, temperature and composition. This conclusion is opposite to that arrived at by Gonzalez & Laws; it is believed that the field-star sample used by them contained too wide a range of ages, evolutionary types and temperatures to be accommodated by the model that they adopted to describe the dependence of Li on the parameters. The Li abundance does not appear set to provide key insights into the formation and evolution of planetary systems.  相似文献   

Amphitheatre-headed canyons of Southern Utah: Stratigraphic control of canyon morphology     

Andrew J. Ryan  Kelin X. Whipple 《地球表面变化过程与地形》2020,45(14):3607-3622

Amphitheatre-headed canyons are common on Earth and Mars and researchers have long sought to draw inferences about canyon-forming processes from the morphology of canyon heads and associated knickpoints, often suggesting that amphitheatre heads indicate erosion by groundwater seepage erosion. However, the conditions and processes that lead to amphitheatre-headed canyon formation have been debated for many years. We consider two hypotheses that attribute the amphitheatre-headed canyon formation to fluvial erosion of strong-over-weak stratigraphy or, alternatively, groundwater spring discharge and seepage erosion. A spatial analysis of canyon-form distribution with respect to local stratigraphy along the Escalante River and on Tarantula Mesa, Utah indicates that canyon form is most closely related to variations in local sedimentary rock strata, rather than inferred groundwater spring intensity. Lateral facies variations that affect the continuity of strong layers can induce or disrupt the formation of amphitheatres. Furthermore, we find that amphitheatre retreat rate is dictated by the interaction of fluvial processes downstream of the amphitheatre headwalls and stratigraphy, rather than waterfall and groundwater processes that likely importantly influence headwall form. We conclude that fluvial erosion of strong-over-weak stratigraphic layering alone is sufficient to form amphitheatres at knickpoints and canyon heads. Thus, we re-affirm that formation process should not be inferred from canyon-head morphology, particularly where a strong-over-weak layering is known or plausible. © 2020 John Wiley & Sons, Ltd.  相似文献   

Reuse of Drinking Water Treatment Waste for Remediation of Heavy Metal Contaminated Groundwater     

Ryan R. Holmes  Megan L. Hart  John T. Kevern 《Ground Water Monitoring & Remediation》2019,39(4):69-79

Lime softening produces an estimated 10,000 metric tons of dry drinking water treatment wastes (DWTW) per year, costing an estimated one billion dollars annually for disposal worldwide. Lime softening wastes have been investigated for reuse as internal curing agents or supplementary cementitious materials in concrete as well as a high-capacity sorbent for heavy metal removal. Lead, cadmium, and zinc are common heavy metals in groundwater contaminated by mine tailings. Cement-based filter media (CBFM) are a novel material-class for heavy metal remediation in groundwater. This study investigated the incorporation of DWTW as a recycled, low-cost additive to CBFM for the removal of lead, cadmium, and zinc. Jar testing at three different metal concentrations and breakthrough column testing using synthetic groundwater were performed to measure removal capacity and reaction kinetics. Jar testing results show as DWTW content increases at low concentrations, removal approaches 100% but at high metal concentrations removal decreases due to saturation or exhaustion of the removal mechanisms. Removal occurs through the formation of metal carbonate precipitates, surface sorption, and ion exchange with calcium according to the preferential series Pb⁺² > Zn⁺² > Cd²⁺. Removal kinetics were also measured through column testing and exceeded estimated calculations derived from batch jar testing isotherms due to the large formation of oolitic metal carbonates. Lead, cadmium, and zinc was concentrated in the column precipitates from 0.29, 0.23, and 20.0 μg/g in the influent solution to approximately 200, 130, 14,000 μg/g in the reacted DWTW-CBFM. The control and DWTW-CBFM columns had statically similar removal for zinc and lead. In the DWTW-CBFM, cadmium had decreased removal of approximately 25% due to proportionately decreased hydroxide content from cement replacement with 25% DWTW. This study shows the potential for DWTW as an enhancement to CBFM, thereby valorizing an otherwise waste material. Furthermore, the concentrative abilities of CBFM through precipitate and oolitic mineral formation could provide a minable waste product and close the waste-product cycle for DWTW.  相似文献   

Computational simulation of slab vibration and horizontal‐vertical coupling in a full‐scale test bed subjected to 3D shaking at E‐Defense          下载免费PDF全文

Jean C. Guzman Pujols  Keri L. Ryan 《地震工程与结构动力学》2018,47(2):438-459

This paper focuses on slab vibration and a horizontal‐vertical coupling effect observed in a full‐scale 5‐story moment frame test bed building in 2 configurations: isolated with a hybrid combination of lead‐rubber bearings and cross‐linear (rolling) bearings, and fixed at the base. Median peak slab vibrations were amplified—relative to the peak vertical shake table accelerations—by factors ranging from 2 at the second floor to 7 at the roof, and horizontal floor accelerations were significantly amplified during 3D (combined horizontal and vertical) motions compared with 2D (horizontal only) motions of comparable input intensity. The experimentally observed slab accelerations and the horizontal‐vertical coupling effect were simulated through a 3D model of the specimen using standard software and modeling assumptions. The floor system was modeled with frame elements for beams/girders and shell elements for floor slabs; the insertion point method with end joint offsets was used to represent the floor system composite behavior, and floor mass was finely distributed through element discretization. The coupling behavior was partially attributed to the asymmetry of the building that was intensified by asymmetrically configured supplemental mass at the roof. Horizontal‐vertical coupled modes were identified through modal analysis and verified with evaluation of floor spectral peaks.  相似文献   

Evaluation of a passive gap damper to control displacements in a shaking test of a seismically isolated three‐story frame          下载免费PDF全文

Hamed Zargar  Keri L. Ryan  Taylor A. Rawlinson  Justin D. Marshall 《地震工程与结构动力学》2017,46(1):51-71

Recent studies have indicated uncertainty about the performance limit states of seismically isolated buildings in very large earthquakes, especially if the isolator displacement demands exceed the seismic gap and induce pounding. Previous research has shown the benefit of providing phased supplemental damping that does not affect the isolation system response in a design event. A phased passive control device, or gap damper, was designed, fabricated, and experimentally evaluated during shake table testing of a quarter scale base‐isolated three‐story steel frame building. Identical input motions were applied to system configurations without a gap damper and with a gap damper, to directly assess the influence of the gap damper on displacement and acceleration demands. The gap damper was observed to reduce displacement demands by up to 15% relative to the isolated system without the gap damper. Superstructure floor accelerations increased substantially because of damper activation, but were limited to a peak of about 1.18 g. The gap damper reduces displacement most effectively if the ground motion contains one or more of the following characteristics: the spectral displacement increases with increasing period near the effective period of the isolation system, the motion is dominated by a single large pulse rather than multiple cycles at a consistent intensity, and the motion has a dominant component aligned with a major axis of the structure. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Subgrid modeling of salt marsh hydrodynamics with effects of vegetation and vegetation zonation          下载免费PDF全文

Guoxiang Wu  Huajun Li  Bingchen Liang  Fengyan Shi  James T. Kirby  Ryan Mieras 《地球表面变化过程与地形》2017,42(12):1755-1768

Vegetation plays a critical role in modifying inundation and flow patterns in salt marshes. In this study, the effects of vegetation are derived and implemented in a high‐resolution, subgrid model recently developed for simulating salt marsh hydrodynamics. Vegetation‐induced drag forces are taken into account as momentum sink terms. The model is then applied to simulate the flooding and draining processes in a meso‐tidal salt marsh, both with and without vegetation effects. Marsh inundation and flow patterns are significantly changed with the presence of vegetation. A smaller area of inundation occurs when vegetation is considered. Tides propagate both on the platform and through the channels when vegetation is absent, whereas flows concentrate mainly in channels when vegetation is present. Local inundation on vegetated platforms is caused mainly by water flux spilled from nearby channels, with a flow direction perpendicular to the channel edges, whereas inundation on bare platforms has contributions from both local spilled‐over water flux and remote advection from adjacent platforms. The flooding characteristics predicted by the model showed a significant difference between higher marsh and lower marsh, which is consistent with the wetlands classification by the National Wetlands Inventory (NWI). The flooding characteristics and spatial distribution of hydroperiod are also highly correlated with the vegetation zonation patterns observed in Google Earth imagery. Regarding the strong interaction between flow, vegetation and geomorphology, the conclusion highlights the importance of including vegetation in the modeling of salt marsh dynamics. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Evaluating simplified models in predicting global seismic responses of a shake table–test building isolated by triple friction pendulum bearings     

Nhan D. Dao  Keri L. Ryan  Hieu Nguyen-Van 《地震工程与结构动力学》2019,48(6):594-610

This paper evaluates the ability of simplified superstructure models, including two shear frame models and a single-story model, in predicting global responses of a full-scale five-story steel moment-frame buildings isolated by triple friction pendulum bearings subjected to earthquake motions. The investigated responses include displacement of the isolation system, roof drift, story drift, and floor acceleration. Mechanical properties of the simplified superstructure models were derived from the modal information of a verified full 3-D model. The comparison between the analytical responses and experimental responses shows that the simplified models can well predict the displacement of the isolation system. Furthermore, the shear-frame models are adequate for predicting floor acceleration when the specimen is subjected to horizontal ground motions. However, when the specimen is subjected to 3-D motions, the shear-frame models un-conservatively predict floor acceleration. The full 3-D model improves the prediction of story drift compared with the simplified models for both horizontal and 3-D motions.  相似文献   

Sub-Micrometre Resolution FIB-SEM-based ToF-SIMS Used to Map Geochemical Zoning in Four Zircon Reference Materials     

Ryan North  Lloyd T. White  Mitchell Nancarrow  Anthony Dosseto  Dominique Tanner 《Geostandards and Geoanalytical Research》2023,47(1):125-142

Zircon geochemistry can vary over micrometre scales; therefore, natural reference materials need to be well characterised before being used to calculate trace element mass fractions in unmeasured samples. Moreover, reference material homogeneity needs to be ensured with the accelerating rate of geoanalytical developments to map mineral chemistry at increasingly finer scales. Here, we investigate trace element zoning in four widely used zircon reference materials: 91500, Mud Tank, Temora and Plešovice, as well as zircon crystals from the Mount Dromedary/Gulaga Igneous Complex, Australia. Sub-micrometre resolution focused ion beam scanning electron microscope (FIB-SEM) based time-of-flight secondary ion mass spectrometry (ToF-SIMS) and 5 μm resolution LA-ICP-MS mapping show that trace elements are zoned in all reference materials, though 91500 exhibited the least zonation. We demonstrate that FIB-SEM-based ToF-SIMS can rapidly resolve variations in trace elements (e.g., U, Th, Sc, Y, Gd, Dy, Yb and Li) at sensitivities down to the μg g^-1 level with a spatial resolution of 195 nm for areas 100 × 85 μm to 959 × 828 μm. Zircon 91500 is recommended for future quantitative analyses provided that (1) the spatial distribution of elements is imaged before analysis of unknown samples and (2) it is used in conjunction with a doped glass as the primary reference material.  相似文献